![]() ![]() ![]() I asked for clarification of this July 25 Microsoft TechCommunity article, which says "Office 2016 & 2019 won't be supported for connecting to Microsoft 365 services, including Exchange Online, starting Oct 2023. The end of mainstream support means Microsoft no longer will provide feature updates or security fixes for these products.īack to Office. Mainstream support for Office 2016 ended in October 2020 and for Office 2019 it will end in October 2023. This October 2025 date is the end of extended support. But Office 2016 support doesn't end until October 14, 2025, which also is the same date that support for Office 2019 ends. Microsoft Office 2013 support ends on April 11, 2023. But these older clients may encounter performance or reliability issues over time. ![]() Important: We won't take any active measures to block other versions of the Office client that are still supported and are up to date, such as Office 2013 with Service Pack 1, from connecting to Microsoft 365 services. Note: Office 2019 and Office 2016 will be supported for connecting to Microsoft 365 (and Office 365) services until October 2023. (Shocker, I know!) The Microsoft docs article about Microsoft 365 services connectivity has two seemingly contradictory statements in the same article. But it is warning those users that they potentially could experience some issues when connecting to Microsoft 365 back-end services after that date. (Or maybe just an overaggressive attempt to get those who want non-subscription Office to move to the cloud?) Microsoft is not going to block Office 2016 and Office 2019 customers from connecting to Microsoft 365 back-end services after October 2023. The good news for those users is this was a false alarm. Recently, some of those users - namely those with Office 2016 and Office 2019 - got a bit of a scare, as it seemed Microsoft had decided to cut off their access to Microsoft 365 back-end services in 2023, which is two years before those products officially exit support. Even though Microsoft is all-in on the cloud, it still is continuing to roll out "perpetual" (non-subscription) versions of Office every few years. ![]()
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![]() ![]() If you encounter problems with your plants within the first 30 days, contact us. ![]() Our guarantee does not cover plants purchased outside your recommended growing zone or those that have received inadequate care. If you're not satisfied within the first five days of receiving your trees and plants, contact us, and we'll help make it right! Please note that proper care and nutrients are necessary for plants to adapt to their new surroundings. If you're ever wondering about your shipment, feel free to drop us an email at Or if you're eager to see your new plant's progress on its journey to you, just use the tracking link from your shipping confirmation email, or click the track my order link at the bottom of our website.īy placing an order with Simply Trees, you agree to the following terms:Īt Simply Trees, we guarantee that your plants and trees will arrive healthy and vibrant. We do this to ensure they spend as little time in transit as possible. We're taking every precautionary measure to protect your plants and trees. Shipping times may vary during peak summer months due to heat. In such cases, we will keep you informed as the health of your plants is our top priority. Occasionally, severe weather forecasts may cause us to delay shipping. Shipping live products can be challenging. ![]() If this happens, we'll be sure to let you know and keep you updated about when you can expect your delivery. We do our best to keep our shipping timelines as promised, but sometimes things outside our control might cause delays. When you place an order with us, we aim to get your new green pals on the road within 1-2 business days. ![]() ![]() ![]() It is bent because of the lone pairs of valence electrons on the chlorine atom and the uneven bond type between each chlorine and oxygen atom. Moreover, the atom with the lowest electronegativity value becomes the central atom as it has to make the maximum number of bonds.Īs a result, chlorine becomes the central atom.įrom the Lewis structure, it is clear that chlorine dioxide or chlorite ion is a triatomic molecule that is bent in shape. The explanation for the same lies in the formal charge distribution that compels the formation of a double bond and a single bond.Įven though the new structure is stable, it is the oxygen atom that usually undergoes bond formation with another nearby atom.Ĭhlorine is the central atom because it is present as the single entity within the chlorine dioxide molecule. One single bond is formed between chlorine and oxygen atoms and a double bond is formed between chlorine and another oxygen atom. Step 4: Find the type of bond formation taking place in one chlorine oxide. ![]() Studying the formal charge distribution in detail also gives us the reason behind the double bond forming between one oxygen and chlorine atom. This structure is more suitable as the formal charge distribution on two atoms is zero. Let us find the formal charge distribution of the above-mentioned molecule. Let us check the correct lewis structure of the ClO2- molecule as below. Therefore the above structure is unstable because there exists another Lewis structure where the formal distribution of some participating atoms is zero. With this, -1 formal charge still remains on another oxygen atom. Here +1 formal charge of the chlorine atom cancels out the -1 formal charge of one of the oxygen atoms. Now we need to calculate the formal charge distribution on chlorine dioxide molecule:įormal Charge = Valence Electrons – Non-Bonding Electrons – ½ Bonding Electrons The reason for the same is each molecule wants to achieve a stable structure that can be gained only with zero formal charge distribution. The aforementioned diagram is one of the lewis structures of chlorine dioxide but, we need to check its stability with the help of formal charge distribution. Step 3: Draw the skeleton of chlorine dioxide. Hence, with no anomaly, the total valence electrons required by one chlorine dioxide would have been 24 which is now 26 with the anomaly of expanded octet in chlorine atom. The third group has the ability to expand its octet and accommodate more valence electrons to achieve a stable molecular structure. It is a classic example of chemistry being full of exceptions!Ĭhlorine belongs to the third group in the periodic table. Here, an anomaly exists with the chlorine atom as it can increase its octet to accommodate more valence electrons. Step 2: Find the valence electrons further needed to stabilize the molecule.īy the octet rule, each element needs eight valence electrons to complete its electronic configuration. ![]() So, the total number of valence electrons available in one chlorine dioxide or chlorite molecule is 20. There are two oxygen molecules in chlorine dioxide so the total is 19.īut chlorine dioxide exists as ClO2- during the formation of a bond, therefore we have one more valence electron available. It is 20 as chlorine has 7 valence electrons and oxygen has 6 valence electrons. ![]() Step 1: Find the total valence electrons in one molecule of chlorine dioxide. Let us follow some steps to draw the Lewis structure of chlorine dioxide: We will draw the Lewis structure of chlorine dioxide with 20 valence electrons. Due to this, the valence electrons in chlorine dioxide or chlorite are 20. This arises from the fact that chlorine dioxide is an unstable molecule and mainly exists as ClO2- during bond formation. Here, it is crucial to understand that chlorine dioxide is a strong anion and oxidizing agent. It might confuse many people as ClO2 comprises 19 valence electrons only. Now, it will be easier to draw the Lewis structure of chlorine dioxide as we know that there are 20 valence electrons in one chlorine dioxide molecule. To begin drawing the Lewis structure of Chlorine dioxide, first, it is essential to draw one for the participating elements.Įlectronic Configuration = 1s2 2s2 2p6 3s2 3p5 The Lewis structure is a pictorial representation of valence electrons taking part in the formation of bonds to produce a new molecule with new properties altogether. Conclusion Lewis Structure of Chlorine Dioxide (ClO2-) ![]() ![]() Get 25 Off POWERPLAY Mouse Pad, when purchased with this mouse. ![]() POWERPLAY compatible for continuous charging both at rest and play. ![]() HERO 25K sensor features sub-micron tracking. The result is our highest performance and most responsive gaming sensor to date, which also unlocks weight reduction due to super-efficient battery size and performance ratio. Gaming Mice G502 LIGHTSPEED g series G502 LIGHTSPEED Wireless Gaming Mouse Iconic G502 design meets pro-grade LIGHTSPEED wireless for ultra-fast, reliable connectivity. Next-gen HERO 16K gaming sensor is capable of 400+ IPS tracking speed across the entire 16,000 DPI range and up to 10x the power efficiency compared to previous generations. It looks and feels exactly the same, which fans will enjoy, but it snips the cord without compromising performance. And the same industry-leading wireless technologies: LIGHTSPEED, HERO 16K and POWERPLAY. 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It also features the next-generation HERO 16K sensor and is POWERPLAY compatible. Logitech G502 LIGHTSPEED is ultra-fast and reliable with performance trusted in competition by esports pros. G502 LIGHTSPEED WIRELESS GAMING MOUSE LIGHTSPEED WIRELESS ![]() ![]() Butterfly your chicken thighs, and then slice them into large, thin escalopes. Separate half of the chopped ginger to be saved for later, and place the other half into a small mixing bowl or ramekin followed by all of the light soy sauce, sake, mirin and honey. Peel your piece of ginger with a teaspoon, and then roughly chop with a sharp knife or cleaver. The cookie is set by the GDPR Cookie Consent plugin and is used to store whether or not user has consented to the use of cookies. The cookie is used to store the user consent for the cookies in the category "Performance". This cookie is set by GDPR Cookie Consent plugin. The cookie is used to store the user consent for the cookies in the category "Other. The cookies is used to store the user consent for the cookies in the category "Necessary". The cookie is set by GDPR cookie consent to record the user consent for the cookies in the category "Functional". The cookie is used to store the user consent for the cookies in the category "Analytics". These cookies ensure basic functionalities and security features of the website, anonymously. Necessary cookies are absolutely essential for the website to function properly. Gordon Ramsay makes the teriyaki sauce himself, but you can use the same sauce for my recipe for his creation. You can also substitute broccoli with other vegetables of your choice. It is best to serve with brown rice, quinoa, or bread. This drool-inducing chicken teriyaki stir-fry dish is easy to make. You can keep it for a week in the refrigerator and for up to two months in the freezer. Then, make a large batch of this easy teriyaki sauce. You can follow the link by clicking the title of the dishes below if you want to look into how to prepare these dishes.īefore you begin, make the sauce as in ingredient B in the recipe above. You can find more information from the original recipe by following the links provided. As a result, many local chefs have developed alternative versions of teriyaki.īelow is a list of teriyaki dishes you can cook quickly with the best teriyaki sauce. This phenomenon is similar to the Chinese Cuisine Kung Pao chicken, which is highly popular internationally. Teriyaki is a Japanese dish that is likely more famous internationally than Japan. Score the chicken for even cooking as the thickness will be the same for every chicken part.ĥ ways to cook innovative dishes with Teriyaki sauce.Tips on how to prepare the best teriyaki chicken Since teriyaki chicken is easy to prepare, it is a perfect dish for working housewives and homemakers who struggle to get food on the dinner table in a limited time. Chinese soy sauce, dark caramelized soy sauce, and Indonesian sweet soy sauce (kicap manis) taste differently from shoyu. Shoyu is a Japanese soy sauce with a distinct aroma and flavor and should not be compromised with different soy sauces. Sake is a Japanese rice wine and is preferred over other types of rice wine for authenticity. Mirin is a sweet Japanese wine that gives the umami to the teriyaki sauce. Therefore, it is worth learning how to make teriyaki sauce at home. This is different from the mediocre teriyaki sauce thickened with cornstarch in certain restaurants. Teriyaki sauce provides a glossy sheen due to volume reduction and caramelization of sugar during preparation. These ingredients provide a constant pull between sweet and salty, a complex flavor that elevates the food to paradise. These ingredients are boiled and reduced to half of the volume, forming a sauce with concentrated flavor. So what is teriyaki chicken? Teriyaki chicken is traditional Japanese food prepared by pan-frying or grilling the chicken and finished by cooking with the teriyaki sauce, which is a combination of Japanese soy sauce, mirin, sake, and sugar. I may receive commissions for purchases made through links in this post. Note: This post may contain affiliate links. Then, you will find some more unique creations from other chefs and food writers to put some unusual twist on the original teriyaki chicken recipe. We will start with chicken teriyaki, which is more common. However, food enthusiasts in western countries may say otherwise because all of these can be cooked the teriyaki way.Ĭulinary globalization is so diverse that it is impossible to define a particular fusion food that belongs to which country. The traditional Japanese will tell you that they are just unrelated food. What are stir-fried beef, meat skewer, burger, and pan-fried salmon recipes in common with the teriyaki chicken recipe? ![]() ![]() Frances’s mother was a stay-at-home mother, while her father worked as a stationary engineer. In Manhattan, New York, Frances Bavier was born in 1902. How dare you try to tell me when to walk and where?’ It’s like yes, you are an actress, but an actress takes direction from the director. Life of Beloved Aunt Bee as Told by Frances Bavier. It was, like, ‘I’m an actress and I know what I’m doing. If you would ask her to move three inches to the right to get in the proper frame, or, ‘Could you stand up when you say that line?’, she’d blow a fuse and refuse. 39K views 8 months ago theandygriffithshow catlady auntbee. Bass on the show and directed episodes of it, said that directing Frances was like stepping on a landmine. ![]() I can only repeat what I was told, but on The Andy Griffith Show, Howard Morris, who played Ernest T. Frances Bavier became America’s favorite aunt when she played the unforgettable Aunt Bee on The Andy Griffith Show. That’s the earliest I can point to where Frances was already getting to be persnickety. Frances Bavier was an Emmy Award-winning actress, who rose to fame for her role in The Andy Griffith Show, but spent her final days locked at home. Eve Arden had trouble with her on The Eve Arden Show. Pop culture historian Geoffrey Mark, author of The Lucy Bookand Ella: A Biography of the Legendary Ella Fitzgerald, opines, “She was a very talented lady, but she was very difficult to work with and nobody could really figure it out. But that is generally not the husband’s point of view and I sympathize entirely with the man who wants his wife to be completely devoted to him and their children.” ![]() I know that many psychologists, particularly women psychologists, hold that a woman can have both a home and a career. To paraphrase Shakespeare, it was not that I loved him less, but I loved acting more. I wanted to be both wife and actress, but learned quickly that this is impossible, at least in my specific case. ![]() However, in a 1964 interview with the Star-Gazette of Elmira, New York, she did reflect, “I married a man who was charming in every way, except that, being non-professional, he had little patience with my dedication to acting. Some have said that she was married to Russell Carpenter, member of the military, from 1928 until they divorced in 1933, while other sources claim she was never wed to anyone. There are conflicting reports on whether or not Frances was married during the early years of her career. ![]() ![]() ![]() ![]() Note: The calculated values in this list were rounded to whole numbers for practical purposes. Shellfish (shrimp, crab, lobster, mussels, oyster, clams, scallops): 165 ☏ (74 ☌) Back From Celsius to Fahrenheit: F (C × 9/5) + 32 From Fahrenheit to Celsius: C (F - 32) × 5/9 Water freezes at 0C (32F) Water boils at 100C (212. The temperature which is taken as T in degrees Celsius (C) is equal to the temperature T which is in degrees we see to convert Fahrenheit to celsius (F).Frozen raw breaded chicken products: 165 ☏ (74 ☌).Poultry pieces (wings, breasts, legs, thighs): 165 ☏ (74 ☌). ![]() Ground meat (beef, veal and lamb): 160 ☏ (71 ☌) What is the range of temperature in degree Fahrenheit, if the conversion formula is F 9/5 C + 32 CBSE Class 11 Linear Inequalities Maths NCERT.Common temperatures in ☏ and ☌īelow there is a list with common temperatures used for cooking, in both degrees Fahrenheit ( ☏) and degrees Celsius ( ☌). If you want to convert 10 degrees Celsius to degrees Fahrenheit, use the Celsius to Fahrenheit formula here.Įxample 2: How to convert 70 Fahrenheit to Celsius?ħ0 degrees Fahrenheit to Celsius is 21.11 ☌ ( 70 ☏ to ☌ is 21.11☌). To convert from Fahrenheit to Celsius (from ☏ to ☌) by using the Fahrenheit to Celsius formula, subtract 32 from the temperature in degrees Fahrenheit, Temperature( ☏), multiply the result by 5 and then divide by 9.Įxample 1: How do you convert 10 Fahrenheit to Celsius? How to convert Fahrenheit to Celsius - Example calculations 1 hour ago &0183 &32 They each field three cars with three drivers. The formula F9/5C + 32 gives the relationship between the temperature in degrees Fahrenheit, F, and the temperature given in degrees Celsius, C. ![]() ![]() ![]() ![]() POSITION DETAILS: Part-time, 40 hours per pay period. Bilingual skills and Basic computer skills preferred. Edwin Espinosa y Sonia Vaca, de la Taquería Yarelis, cuentan qué hace tan. Must have food safety knowledge in handling good. Una taquería en Fresno, California, se ha hecho famosa por su burrito anaconda, que mide dos pies y medio de largo. Must be able to communicate effectively with other food server personnel, hospital employees, physicians, and the public, and work independently using good judgement and common sense. Must have knowledge of use and care of equipment and utensils. Should possess the ability to service in quantity and proper portion control. Must be able to read, write legibly, understand, and follow oral and written English instruction. Serve Safe Certification or Food Handlers Permit preferred. REQUIREMENTS: A minimum six (6) months previous kitchen experience in an acute healthcare facility OR a minimum six (6) months previous work experience preferred. May be assigned to work at the cash register during breakfast meal service on the weekdays and lunch meal service on weekends. (KFSN) - The masterminds at Taqueria Yarelis have gained an even bigger following on Facebook thanks to this video of their 'Anaconda' burrito. You don't want to miss it.Accountable for performing a variety of food service duties to assist in setup, preparation, assembly, and serving of cafeteria meals. Even I want to go there now! Check out the video below to see Martinez in action. If no one ever finishes this burrito again, and it's only Martinez, he will still have done a huge service for Taqueria Yareli's, because it's probably safe to bet that this story has gotten the restaurant a ton of free publicity. Let's take a minute to respect this feat before we all start jumping in. ![]() He's 18th in the world for competitive eating, so just because he can do it doesn't mean we all can. There will be others who will come to do this." He says so himself: "Mark my words, I won't be the last. However, as Martinez is the first, he feels certain he won't be the last. My only answer to that is, I hope so! Anaconda Burrito creator Edwin Espinoza says that many others have come along in hopes of undertaking this task, but none yet had been successful. Restaurants in Fresno, Fresno Restaurants, Downtown restaurants, Best Downtown restaurants, Fresno restaurants, New Year Parties in Fresno, Christmas Special in Fresno. ![]() "Burritos are my specialty," Martinez told KFSN-TV, "this will definitely be the longest burrito I've eaten." If that doesn't give you an idea of the task Martinez overtook, then you might as well skip right down to that video. Usually the burrito is sliced up and served to a family of four. According to KFSN-TV, renowned competitive eater Pablo Martinez was the first person to come along and eat an entire Anaconda Burrito. That's right, you're about to see it yourself in the video below. Taqueria Yareli's of Fresno, California, sells this burrito, and it's called "The Anaconda Burrito." If that name doesn't scare you away, this picture of it will:Įven scarier? Watching someone come along and eat it right up in just thirteen minutes. I don't know how many Chipotle burritos would equal this giant one … I just know it has to be a lot. If you think a Chipotle burrito is big, imagine eating about 10 of those. Imagine trying to eat a 3-foot-long, 5-1/2-pound burrito. ![]() ![]() It’s unlikely to come to the UK officially, but you never know… Keep up to date with the latest EV news £28,301) but that’s before local taxes or state EV benefits are taken into account. The Ford F-150 Lightning electric truck goes on sale in 2022, though you can reserve one now - as long as you’re in the US. New Ford F-150 Lightning price and release date Pricing for the F-150 Lightning begins around $40,000 The F-150 Lightning also supports over-the-air software updates, to keep the electric setup constantly updated and potentially improving range and performance over time. There is a sensor on the dashboard to make sure you’re paying attention while you’re using it though, so don’t think it’ll let you slack off behind the wheel. As well as ringing bells of the Blue’s Clues children’s TV show, it’s like Tesla’s Autopilot system - capable of accelerating, braking and steering for you on certain roads. The Ford F-150 Lightning is equipped with ‘BlueCruise’ tech. New Ford F-150 Lightning technology ‘BlueCruise’ semi-autonomous tech features here There’s also a 12-inch digital driver’s display rather than analogue dials. Official performance figures are yet to be released, but Joe Biden, you know, the President of the United States, had a go in a prototype and said it could do 0-60mph in ‘4.3 or 4.4 seconds’. Queue the train towing videos on YouTube… Both have a colossal 1,050Nm of torque, though. The Standard truck gets a healthy 432hp, though that’s cranked up to 571hp in the Extended Range version. You’d suspect if you maxed out the 907kg payload, that would drop a bit.Įvery version of the Ford F-150 uses a dual-motor setup, with one on either axle for an all-wheel-drive setup. That’s assuming you’re not carrying anything. The Extended version of the F-150 will be capable of up to 300 miles between charges The former will be able to cover up to 230 miles on a charge, with the latter capable of 300 miles. ![]() ![]() Ford hasn’t said how large the batteries in this EV are, though it will offer ‘Standard’ and ‘Extended’ range versions. Now it’s something of a cheesy reference to its electric power. That name ringing a bell? Well, the Ford F-150 Lightning was once a V8-powered performance version of the F-150 pick-up truck. Although that’s not saying much… New Ford F-150 Lightning batteries and performance The F-150 Lightning uses a dual-motor setup as standard As a result, the Lightning’s the most aerodynamically efficient Ford F-150 ever. Other changes to the design compared with the standard F-150 include a smoothed-out front grille, which makes sense considering there’s no engine to cool. ![]() ![]() ![]() ![]() The GRI has established a three-step process for determining the Schedule B code in such situations the introduction to the official Schedule B publication contains the relevant passage. Rule 3 of the General Rules of Interpretation (GRI) of the Harmonized Tariff Schedule addresses composite goods, mixtures, and items that are sold in a set. Some sets, however, are harder to classify. For example, an unassembled bicycle that is sold in a box containing the bicycle frame, handlebars, pedals, and seat is classified as a bicycle (because the item is sold as one unit) and not as several different components. Shipping multiple items as a set: For the most part, determining a product’s Schedule B code is straightforward.Use this database to determine whether other exporters or importers requested a ruling on the same or a similar product and, if so, what that ruling was. CROSS contains official, legally binding rulings from other exporters’ and importers’ requests for Schedule B codes. If your product is difficult to classify, the Customs Rulings Online Search System (CROSS) database can help you find its Schedule B code. The Schedule B search tool is the most commonly used method for classifying products. The site provides training resources to help you better identify for your Schedule B number, as well as contact information for assistance. The Census Bureau offers a free, widely used online Schedule B search tool that can help you classify your products. ![]() How to Identify Your Product’s (U.S.) Schedule B Code
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